A measurement procedure is linear when there is a mathematically verified straight-line relationship between the measured and true values. It is an important parameter as it allows linear interpolation of results between points.
A linear (straight-line) fit describes a relationship where the measuring system is linear. A polynomial fit describes a relationship where the measuring system is nonlinear. In evaluating linearity, a nonlinear polynomial fit is compared against a linear fit. Typically the 2nd and 3rd order polynomial fits are of interest:
Bias due to nonlinearity is measured as the difference between the linear fit and the best fitting polynomial fit.
From the Statistical Reference Guide for Analyse-it 6.24.0: https://analyse-it.com/docs/user-guide/measurement-systems-analysis/trueness/linearity
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